ARDUINO
Download and Install Arduino Environment: http://arduino.cc/en/Main/Software
Reference Library: http://arduino.cc/en/Reference/HomePage
Getting Started Guide: http://arduino.cc/en/Guide/Windows#toc2
XIVELY
Get Arduino Library: https://github.com/xively/xively_arduino/archive/master.zip
Add Xively library to Arduino software libraries
Set up HTTP Client: https://github.com/amcewen/HttpClient/archive/master.zip
Add HTTP Client to Arduino software libraries
TUTORIAL
Connect Sensors to Xively: https://xively.com/dev/tutorials/arduino_wi-fi/